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Diimide
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Diimide, also called diazene or diimine, is a compound having the formula HN=NH. It exists as two geometric isomers, E (trans) and Z (cis). The term diazeneSulfur diimide (454 words) [view diff] exact match in snippet view article find links to article
are chemical compounds of the formula S(NR)2. Structurally, they are the diimine of sulfur dioxide. The parent member, S(NH)2, is of only theoretical interestN-heterocyclic silylene (4,605 words) [view diff] exact match in snippet view article find links to article
Five-membered N-heterocyclic silylenes are synthesized from two-carbon diimine or diamine precursors. Reaction with metallic lithium yields a lithiatedTetrazene (252 words) [view diff] exact match in snippet view article find links to article
Paul J. (2018). "Synthesis and Electronic Structure Diversity of Pyridine(diimine)iron Tetrazene Complexes". Inorganic Chemistry. 57 (16): 9634–9643. doi:10Francis S. Mair (1,093 words) [view diff] exact match in snippet view article find links to article
in polymerization, led a further research in 2016 on the use of enamine–diimine cobalt complexes in isoprene polymerization. Both these researches indicatedDNA-binding metallo-intercalators (1,121 words) [view diff] exact match in snippet view article find links to article
metallo-intercalator and the DNA sequence. For example, the ligand 5,6-chrysenequinone diimine (chrysi) and its analogues are designed to be too wide to fit inside theQuinone (1,851 words) [view diff] exact match in snippet view article find links to article
Quinone imine – where one O is replaced by N, illustrated by NAPQI Quinone diimine – where both O's are replaced by N's, illustrated by the antiseptic ambazonePhotoinduced electron transfer (448 words) [view diff] exact match in snippet view article find links to article
of the spectroscopy, photochemistry and electrochemistry of [M(CO)4(α-diimine)] complexes, M=Cr, Mo, W" Antonín Vlcek Coord. Chem. Rev. 230 (2002) 225-242Salt metathesis reaction (812 words) [view diff] exact match in snippet view article find links to article
multiple names: authors list (link). Mashima, Kazushi (2020). "Redox-Active α-Diimine Complexes of Early Transition Metals: From Bonding to Catalysis". BulletinEthylenediamine (1,166 words) [view diff] exact match in snippet view article find links to article
the diamine condenses with 4-Trifluoromethylbenzaldehyde to give to the diimine. The salen ligands, some of which are used in catalysis, are derived fromMagnesium(I) dimer (2,796 words) [view diff] exact match in snippet view article
N-ligand. This reaction is carried out through potassium reduction of the α-diimine, MeDipDAB and Mg(II) chloride in tetrahydrofuran (THF). It can be notedCycloaddition (1,346 words) [view diff] exact match in snippet view article find links to article
n-butyllithium is a Stork enamine / 1,2-addition cascade reaction: Iron[pyridine(diimine)] catalysts contain a redox active ligand in which the central iron atomDiiminoisoindole (80 words) [view diff] exact match in snippet view article find links to article
Diiminoisoindole Names IUPAC name 3-Iminoisoindol-1-amine Other names Isoindoline-1,3-diimine; Phthalimide diimide Identifiers CAS Number 3468-11-9 3D model (JSmol)O-Phenylenediamine (547 words) [view diff] exact match in snippet view article find links to article
coordination chemistry. Oxidation of metal-phenylenediamine complexes affords the diimine derivatives. OPD condenses with salicylaldehyde to give chelating SchiffLesley Yellowlees (1,143 words) [view diff] exact match in snippet view article find links to article
Robertson, N. (2005). "Synthesis, Structure, and Properties of [Pt(II)(diimine)(dithiolate)] Dyes with 3,3'-, 4,4'-, and 5,5'-Disubstituted Bipyridyl:Phosphenium (1,948 words) [view diff] exact match in snippet view article find links to article
also been reported. Reaction of PI3 with the α-diimine yields the NHP cation by reduction of the diimine and oxidation of iodine. According to X-ray crystallographyCatalytic chain transfer (1,429 words) [view diff] exact match in snippet view article find links to article
(2003). "Polymerization of Methyl Methacrylate Using Four-Coordinate (α-Diimine)iron Catalysts: Atom Transfer Radical Polymerization vs Catalytic ChainOrganoiron chemistry (2,879 words) [view diff] exact match in snippet view article find links to article
A. J. P. and Gibson, V. C., "Correlation of Metal Spin-State in alpha-Diimine Iron Catalysts with Polymerization Mechanism", Inorg. Chem., 2007, 46,W. Harmon Ray (1,312 words) [view diff] exact match in snippet view article find links to article
Prediction of Polymer Properties for Ethylene Polymerization over Nickel-Diimine Catalysts". I&EC Research, 44, 5932–5949 (2005). Wells, G. J. and W. HStefan Bernhard (1,019 words) [view diff] exact match in snippet view article find links to article
University of Fribourg for "synthesis and properties of adamantane bridged diimine ligands and their Ru(II) and Os(II) complexes" under Prof. Dr. Peter BelserHair coloring (4,616 words) [view diff] exact match in snippet view article find links to article
4-diaminobenzene derivative to the quinone state. 2) Reaction of this diimine with a coupler compound (more detail below). 3) Oxidation of the resultingMagnesium monohydride (3,958 words) [view diff] exact match in snippet view article find links to article
Wu (2009). "Magnesium−Magnesium Bond Stabilized by a Doubly Reduced α-Diimine: Synthesis and Structure of [K(THF)3]2[LMg−MgL] (L = [(2,6-iPr2C6H3)NC(Me)]22−)"Mark S. Wrighton (2,775 words) [view diff] exact match in snippet view article find links to article
discovered photoluminescence in a new class of rhenium (I) tricarbonyl diimine complexes. In the 1980s, he and his co-workers developed molecule-based6PPD (1,662 words) [view diff] exact match in snippet view article find links to article
aminoxyl radicals and was first thought to degrade only to the quinone diimine, but has since been understood to continue to oxidize to quinones, amongstCycloheptyne (249 words) [view diff] exact match in snippet view article find links to article
Cycloheptyne can be prepared starting from N, N'-diisopropylcycloheptane-1,2-diimine. By reaction with ammonia and hydroxylamine-O-sulfonic acid in methanolMetal complexes of diamines (887 words) [view diff] exact match in snippet view article find links to article
HDO In some redox-active metals, en can undergo dehydrogenation to give diimine complexes: [Ru(H2NCH2CH2NH2)3]2+ + O2 ⇌ [Ru(H2NCH2CH2NH2)2(HN=CHCH=NH)]2+Julia Weinstein (459 words) [view diff] exact match in snippet view article find links to article
Weinstein; Michael W. George; Kirk S. Schanze (1 July 2001). "Photophysics of diimine platinum(II) bis-acetylide complexes". Inorganic Chemistry. 40 (16): 4053–4062Gallylene (2,871 words) [view diff] exact match in snippet view article find links to article
coworkers demonstrated that the dimer composed of two gallylenes with a-diimine ligands was able to react with organic azides. This gallylene's reactivityGeorgiy B. Shul'pin (1,912 words) [view diff] exact match in snippet view article find links to article
Selectivities in C-H Activations of Toluene and p-Xylene at Cationic Platinum(II) Diimine Complexes.”, J. Am. Chem. Soc. 2001, 123, 6579-6590. doi:10.1021/ja010277eIminoiodinane (2,476 words) [view diff] exact match in snippet view article find links to article
(1993-06-01). "Asymmetric alkene aziridination with readily available chiral diimine-based catalysts". Journal of the American Chemical Society. 115 (12): 5326–5327Borirene (3,091 words) [view diff] exact match in snippet view article find links to article
(2023-12-18). "A Journey from Benzoborirene to Benzoborole-Supported 1,2-Diimine and Antiaromatic Borolediide". Angewandte Chemie International Edition